Bianca, a woman from the future, arrives to take Chris's powers, and Leo learns that she is actually part of an assassin family of witches. Meanwhile, Paige decides to move in with Richard, while Phoebe ponders joining Jason in Hong Kong.

The Charmed Ones help out Leo's mentor, Gideon, when he wants to find out who cast the spell of darkness over a magic school and conjured the headless horseman who has been beheading the teachers. Meanwhile, Phoebe goes on a vision quest.

With Piper away at magic school and Phoebe without her active powers, overworked Paige conjures Mr. Right for stress relief but, unknowingly, releases his evil twin, Mr. Wrong.

When Paige encounters Captain Black Jack Cutting, an 18th century pirate in search of the Fountain of Youth, the curse on his life becomes her problem. Meanwhile, Leslie manipulates a contest in order to spend time with Phoebe, Leo fights with the creature that caused him to kill an Elder, and a mysterious federal agent comes to town to investigate the Halliwells.

At the same time that the Avatars are planning to transform the world into their envisioned utopia, Zankou kidnaps Brody and is forced to cast a paranoia spell on the Halliwell sisters.

The sisters scramble to recover Pandora's Box when it falls into the hands of a shapeshifting demon who intends to open it and fill the world with all of its sorrows. Meanwhile, Paige's Whitelighter side rises to the surface, when she begins hearing calls from the Elders, and Leo and Piper clash over parenting issues - namely raising magical children.

When Piper goes for a job interview with a corporate recruiter, she's shocked to learn that the background check of her assumed identity was that of a woman wanted for murder. Meanwhile, Phoebe has a premonition of Dex being in an earthquake.

The Angel of Death returns to visit the Charmed Ones but they're shocked to learn that he's there for Leo. To try to stop him from taking Leo, Piper casts a spell that backfires, making every man a Leo lookalike, forcing Piper to take drastic measures and ask the Elders and the Avatars for help. Meanwhile, Billie continues her search for the truth behind her sister's disappearance.

During Chinese New Year, a demon attempts to steal a mystical wooden staff, that's protected by the Zodiacs and they enlist the aid of Piper. Meanwhile, Phoebe enjoys her new place by throwing a housewarming party that gets out of control; a monk teaches Billie how to use her power of projection to find her sister; Paige tries to get through to Henry about her magical abilities.

Piper and Phoebe devise a plan to recover Leo. Meanwhile, Paige rescues her new charge from a Darklighter; Billie is forced to make an important decision.