The Charmed Ones help out Leo's mentor, Gideon, when he wants to find out who cast the spell of darkness over a magic school and conjured the headless horseman who has been beheading the teachers. Meanwhile, Phoebe goes on a vision quest.

When Piper is kidnapped and cocooned by the Spider Demon, and becomes Chris infected with the Demon's venom, causing him to mutate into a spider, Paige, Phoebe and Leo try to rescue them. Meanwhile, Leo finally learns why Chris resents him.

With Piper away at magic school and Phoebe without her active powers, overworked Paige conjures Mr. Right for stress relief but, unknowingly, releases his evil twin, Mr. Wrong.

Under the pressure that the Halliwell sisters will discover his evil plot, Gideon conspires with two demons to make Piper, Phoebe and Paige part of ""Witch Wars"", a new demonic reality television show where demon contestants compete in a series of contests to hunt down the Charmed ones.